Comparative study of a solid film dewetting in an attractive substrate potentials with the exponential and the algebraic decay
نویسنده
چکیده
Abstract We compare dewetting characteristics of a thin nonwetting solid film in the absence of stress, for two models of a wetting potential: the exponential and the algebraic. The exponential model is a one-parameter (r) model, and the algebraic model is a two-parameter (r, m) model, where r is the ratio of the characteristic wetting length to the height of the unperturbed film, and m is the exponent of h (film height) in a smooth function that interpolates the system’s surface energy above and below the film-substrate interface at z = 0. The exponential model gives monotonically decreasing (with h) wetting chemical potential, while this dependence is monotonic only for the m = 1 case of the algebraic model. Linear stability analysis of the planar equilibrium surface is performed. Simulations of the surface dynamics in the strongly nonlinear regime (large deviations from the planar equilibrium) and for large surface energy anisotropies demonstrate that for any m the film is less prone to dewetting when it is governed by the algebraic model. Quasiequilibrium states similar to the one found in the exponential model [6] exist in the algebraic model as well, and the film morphologies are similar.
منابع مشابه
On dewetting dynamics of solid films of hydrogen isotopes and its influence on tritium spectroscopy
The dewetting dynamics of solid films of hydrogen isotopes, quench-condensed on a graphite substrate, was measured at various temperatures below desorption by observing the stray light from the film. A schematic model describing the dewetting process by surface diffusion is presented, which agrees qualitatively with our data. The activation energies of different hydrogen isotopes for surface di...
متن کاملMorphologies and kinetics of a dewetting ultrathin solid film
Abstract The surface evolution model based on geometric partial differential equation is used to numerically study the kinetics of dewetting and dynamic morphologies for the localized pinhole defect in the surface of the ultrathin solid film with the strongly anisotropic surface energy. Depending on parameters such as the initial depth and width of the pinole, the strength of the attractive sub...
متن کاملModelling thin-film dewetting on structured substrates and templates: bifurcation analysis and numerical simulations.
We study the dewetting process of a thin liquid film on a chemically patterned solid substrate (template) by means of a thin-film evolution equation incorporating a space-dependent disjoining pressure. Dewetting of a thin film on a homogeneous substrate leads to fluid patterns with a typical length scale, that increases monotonously in time (coarsening). Conditions are identified for the amplit...
متن کاملNot spreading in reverse: The dewetting of a liquid film into a single drop
Wetting and dewetting are both fundamental modes of motion of liquids on solid surfaces. They are critically important for processes in biology, chemistry, and engineering, such as drying, coating, and lubrication. However, recent progress in wetting, which has led to new fields such as superhydrophobicity and liquid marbles, has not been matched by dewetting. A significant problem has been the...
متن کاملELECTROCHEMICAL BEHAVIOR OF GC, Pt AND Au ELECTRODES MODIFIED WITH THIN FILM OF COBALT HEXACYANOFERRATE
0A thin film of cobalt hexacyanoferrate (CoHCF), an analogue of mixed-valence Prussian blue, was deposited electrochemically on the glassy carbon, platinum and gold electrode surfaces in 0.5M KC1 solution. The electrochemical behavior of these modified electrodes show three couples of redox peaks by CV in a supporting electrolyte solution of 0.5M NaCl, whereas for Au modified electrode only ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2013